On the Hydrides of B, C, N, O and F

نویسندگان

  • Michael J. Bucknum
  • Eduardo A. Castro
چکیده

I have had thoughts on the hydrides possible for B, C, N, O & F, and particularly for N there seems to be some interesting undiscovered possibilities. Thus I am aware of: (1) the hydrides of B have been investigated & elucidated by Stock et al. and Lipscomb et al. & I have tried to read this literature, but I am not able to get a reliable source, and I understand that the hydrides of B differ from those of C, N, O and F in that they exhibit in some cases exceptions to covalent, electron-pair, 2center bonds, in the form of electron deficient, 3-center bonds, and that there are innumerable hydrides of B, like the innumerable hydrides of C, which in some cases display resonance effects in their hydroboron structures as suggested by Pauling et al., and (2) the hydrides of C are innumerable and they universally possess Lewis octet, covalent, electronpair, 2-center bonds, with rare exceptions in which a hydrocarbon has perhaps C atoms in strained geometries which may possess coordination numbers different than 3 or 4, they are successfully described by Pauling's VB theory and Mulliken's MO theory, and some hydrocarbons display classical quantum mechanical resonance effects as predicted by Pauling et al. including the archetypal system benzene.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Amitraz Poisoning; A case study

A m i t r a z, a n i ns e c t i c i d e /a ca ri c i de of the f o r m a m i d i n e p e st i c i d e s group, is a ? 2 a d r e n e r g i c ag on i st a nd of t he a m i d i ne c h e m i ca l f a m il y generally us e d to c o n t r ol animal e c top a r a s i t e s. Poisoning due to am i t r a z i s r a r e and character...

متن کامل

A Study on the Electronic and Structural Properties of C12X8 (X = C, B) and Their Interaction with Glycine with Potentially Drug Delivery Vessels

In this paper, the structural properties of C20 and C12B8 fullerene interacting with glycine based onthree active sites of glycine and one C atom or one B atom in C12B8 were analyzed through thedensity functional theory. It was found out that the binding of glycine to C12B8 generated a complex.Our results were extremely relevant in order to identify the potential applications of functionalizedC...

متن کامل

Parabolic starlike mappings of the unit ball $B^n$

Let $f$ be a locally univalent function on the unit disk $U$. We consider the normalized extensions of $f$ to the Euclidean unit ball $B^nsubseteqmathbb{C}^n$ given by $$Phi_{n,gamma}(f)(z)=left(f(z_1),(f'(z_1))^gammahat{z}right),$$  where $gammain[0,1/2]$, $z=(z_1,hat{z})in B^n$ and $$Psi_{n,beta}(f)(z)=left(f(z_1),(frac{f(z_1)}{z_1})^betahat{z}right),$$ in which $betain[0,1]$, $f(z_1)neq 0$ a...

متن کامل

Lie $^*$-double derivations on Lie $C^*$-algebras

A unital $C^*$ -- algebra $mathcal A,$ endowed withthe Lie product $[x,y]=xy- yx$ on $mathcal A,$ is called a Lie$C^*$ -- algebra. Let $mathcal A$ be a Lie $C^*$ -- algebra and$g,h:mathcal A to mathcal A$ be $Bbb C$ -- linear mappings. A$Bbb C$ -- linear mapping $f:mathcal A to mathcal A$ is calleda Lie $(g,h)$ -- double derivation if$f([a,b])=[f(a),b]+[a,f(b)]+[g(a),h(b)]+[h(a),g(b)]$ for all ...

متن کامل

Effect of Dietary Crude Protein Level on UT-B Expression and Nitrogen Efficiency in Growing Baluchi Male Lambs Fed Low or High Concentrate Diets

An experiment was carried out to evaluate how interactions between forage to concentrate ratio and dietary crude protein level may alter nitrogen efficiency and UT-B expression in growing Baluchi male lambs. Four Baluchi male lambs [30 ± 2 kg BW] were used in a 4 × 4 latin square design with 28-d periods and a 2 × 2 factorial arrangement of dietary treatments. The treatments fed forage: concent...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2011